The isotope ratios provided were computed by averaging the instantaneous ratios for each fractional scan in the data range of interest. Background was subtracted by assuming that an initial value measured prior to introduction of atmospheric gas into the manifold followed the same trend during atmospheric analysis as the gas being measured. Initial background values for the first analysis region were computed by averaging peak areas at each m/z +/- 0.4 for the last 6 scans of the first background region. Initial background values for the second analysis region were computed by averaging the peak areas at each m/z +/- 0.4 for the last 5 scans of the second background region. Caron isotope ratios are given as per mil deviations (delta 13_C) from the Vienna Pee Dee Belemnite standard. Volume mixing ratios were computed by subtracting a constant background value, corresponding to the initial background described above, from the average peak area at each m/z +/- 0.4 during each 7 mbar analysis region.